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Spain clinched a 1-0 victory over Croatia in Gdansk to top Group C. Jesus Navas scored the only goal of the match on 88 minutes.
Spain collected seven points and topped the Group C.
In the second match, Italy scored twice to hand third defeat to the Republic of Ireland and booked the second place in Group C.
Cassano headed home from an Andrea Pirlo corner on 35 minutes, before Balotelli volleyed a brilliant second on 90 minutes.